Abstract
The nuclear magnetic resonance spectrum of
jacozine indicates that this base has structure (V) and is thus derived from
seneciphylline (IV) by epoxidation at the ethylidene double bond. This
structure was confirmed by conversion of jacozine into seneciphylline by
reaction with potassium selenocyanate. The same reagent converts jacobine into
senecionine.
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24 articles.
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