Author:
Acott B,Beckwith ALJ,Hassanali A
Abstract
Treatment of primary
carboxamides with lead tetraacetate in benzene-alcohol mixtures or neat alcohol
affords a convenient, flexible, and efficient method for the preparation of
N-substituted carbamic acid esters. The reaction is applicable to amides and alcohols
of a wide range of structural types including compounds containing oleflnic,
ester, aromatic, and other reactive functions. The reaction mechanism appears to involve
intermediate formation of isocyanates.
Cited by
28 articles.
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