Abstract
The recently revised
structure (4) proposed for pseudohypericin has been confirmed by spectroscopic data
and two independent syntheses. The phenanthroperylene quinones (7) and (a), the
former corresponding to fringelite F, have been synthesized from the corresponding
anthrones (16) and (17).A revised structure for
cyclopseudohypericin (5) has been established on the basis of spectroscopic evidence.
Other reactions of pseudohypericin are discussed.
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