Author:
Sipos Pal,Hefter Glenn,May Peter M.
Abstract
A detailed study of highly concentrated aqueous alkaline aluminate solutions
has been made by hydrogen electrode potentiometry in cells with liquid
junction at 25°C in 8 M Na(ClO4) media. Measurements
were performed over the total concentration ranges 0·1 M <
[NaOH]T < 4·0 M and 0·02 M
< [AlIII]T <
3·2 M, and at total concentration ratios of 6·92 ≥
[OH-]T/[AlIII]T
≥ 4·3. Nernstian electrode behaviour was observed at
[NaOH]T ≤ c. 2 M in
pure NaOH/NaClO4 mixtures. At low
[AlIII]T the data were
consistent with the formation of only the well known
Al(OH)4-(aq) species but there is
clear evidence of a systematic release of hydroxide as
[AlIII]T and
[NaOH]T increase. The data are consistent with
the formation of polymeric aluminate complexes having a stoichiometry of
Alq(OH)3q - rr+
(q = 4–7, q + r = 1 or 2). However, unequivocal
identification of these species is difficult on account of strong correlations
in the data and the possible effects of ion-pairing.
Cited by
44 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献