Author:
Green Alison J.,Van Victor,White Jonathan M.
Abstract
Accurate low-temperature X-ray structural studies on
trans-4-trimethylsilylcyclohexyl
p-nitrobenzene- sulfonate (31) and
cis- and
trans-4-trimethylstannylcyclohexyl
p-nitrobenzenesulfonates (32) and (33) failed to
demonstrate the presence of any significant structural effects due to a
σM-C-σC-C-σ*C-O
through-bond interaction between the C–M σ donor orbital and the
σ*C-ONs acceptor orbital.
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