Author:
Birch AJ,Corrie JET,Subba Rao GSR
Abstract
A synthesis of the
optically inactive form of the natural sesquiterpene
davanone (1)together with three stereoisomers has been
carried out as in Scheme. Although not
subject to steric control, the synthesis confirms the structure of davanone, and leads to the suggestion that the relative
stereochemistry may be that shown in (16). The preparation and some reactions
with carboxylic acids of 3-methylbut-2-enyllithium
are described.
Cited by
39 articles.
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