Abstract
The compounds mentioned in
the title were synthesized from 2,5-anhydro- D-glucitol.
2,5-Anhydrogalactitolforms complexes with cations involving the two hydroxyl
groups in the ring and the ring-oxygen atom; 2,5-anhydroallitol does not form
such complexes. The reaction of cis-(2,5- dihydrofuran-2,5-diyl)dimethyl
dibenzoate (5) with iodine and silver acetate was found to be unusual, hydroxylation
occurring from the unhindered side.
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