Author:
Boddy IK,Boniface PJ,Cambie RC,Craw PA,Huang Z,Larsen DS,McDonald H,Rutledge PS,Woodgate PD
Abstract
Gentle heating of
allyloxyanthraquinones with sodium dithionite in dimethylformamide/water effects
a rapid and controlled rearrangement to give high yields of
2-allylhydroxyanthraquinones.Starting from quinizarin,
key intermediates for two synthetic routes to 4-demethoxydaunomycinone have
been prepared from products by means of two such reductive Claisen
rearrangements.
Cited by
36 articles.
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