Author:
Fenby DV,Chand A,Inglese A,Grolier JE,Kehiaian HV
Abstract
Extensions of the ideal
associated solution theory which take into account intermolecular interaction
and/or size factors are derived and applied to triethylamine+ CHCl3
and diethyl ether+CHCl3. Evidence is presented for
non-hydrogen-bonding specific interactions between the unlike molecules in
these systems. Theories that do not take this into consideration are likely to
be unsatisfactory for the determination of hydrogen-bond properties. With
respect to the evaluation of ?net complex formation? properties, the extensions
considered do not represent significant improvements of the simple theory. The
molar enthalpies of mixing of triethylamine+CH3CCl, and diethyl
ether+ CH3CCl3 have been measured at 288.15 and 298.15 K.
Cited by
17 articles.
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