Author:
Diamantis AA,Sparrow GJ,Snow MR,Norman TR
Abstract
The reaction between
dinitrogen oxide and Ru(NH3)5OH22+
to form the dinitrogen complexes of pentaammineruthenium(II)
was investigated. At high pressures of N2O the Br, I, BF4
and PF6 salts of Ru(NH3)5N2O2+
were isolated. The compounds were characterized and their aqueous chemistry compared
with that of the corresponding salts of Ru(NH3)OH22+
whose preparation and characterization are also reported here. The infrared
spectra and X-ray powder patterns of the dinitrogen oxide complexes are
reported.
Cited by
30 articles.
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