Author:
Dyke SF,Spray CR,Kilminster RA
Abstract
Some time ago it was
reported that 4,6,11,11a-tetrahydro-1H-benzo[b]quinolizin-2(3H)-ones are
produced when N-benzylaminoacetaldehyde dialkyl acetals react with methyl vinyl
ketone in acid solution. These structures have now been confirmed, the scope of
the reaction broadened and the conformations of the products investigated. Some
of these ketones have been treated with phenyl- magnesium bromide, but no
useful central nervous system activity has been found for any of the tertiary
alcohols produced.
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