Abstract
The reaction of Viehe's salt
(Me2N+=CCl2Cl-) with various
carbohydrate diols (manno, allo) in
the presence of a base is reported, the products being, after hydrolysis,
either carbonate (with pyridine) or the carbamate (with triethylamine). A
rationalization of the two different types of product formed is given in terms
of the stereoelectronic control proposal by Deslongchamps.
Cited by
13 articles.
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