Abstract
Reactions between AgC2Ar
(Ar = Ph or C6F5) and RhCl(PPh3)3
or IrCl(CO)(PPh3)2 have given hexanuclear heteroatom
cluster compounds M2Ag4(C2Ar)8(PPh3)2
(M = Rh or Ir), and the zwitterionic complexes {[Ag(PPh3)]+
[M(C2C6F5)4(PPh3)2]-}
and {[Ag(PPh3)]2+ [Rh(C2C6F5)5(PPh3)]
2-}.The structures of these complexes are described and
discussed, together with possible reactions by which they may be formed.
Cited by
19 articles.
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