Abstract
The molal cryoscopic
constant in molten pyridinium chloride (m.p. 146.0�) has been found to be 17.4�
(subject to confirmation by calorimetry) and the cryoscopic heat of fusion,
2310�40 cal mole-1. In pyridinium chloride as a solvent, iodides
appear to dissociate completely while bromides do not yield the expected
depression possibly because of solid solution. Tetraalkylammonium and alkyl-pyridinium
halides of high molecular weight are ideally dissociated in extremely dilute
solution but with increasing concentration apparently form micelles.
Cited by
27 articles.
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