Abstract
The activities of silver
chloride in molten MgCl2-KCl (32.5 : 67.5 mole %) and in molten MgCl2-NaCl-KCl
(50 : 30 : 20 mole %) as solvent at 475�C have been determined by measuring the
e.m.f. of the galvanic cell:
����������������� Ag | AgCl
(in melt) || melt | Cl2 (graphite)
as a function of silver
chloride concentration in the solution. The extent of deviations from ideal
behaviour in these solvents has been compared with those observed in other
mixed chloride solvents and the results are interpreted on the basis of the
interactions of the various solvent cations.
Cited by
3 articles.
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