Abstract
Partial molal
volumes, V�, at 25�C were measured for sucrose, ascorbic acid and aspirin in
the solvents water, formamide, N,N-dimethylformamide and methanol. The
dependence of V� on solvent compressibility enabled an estimate to be made of
the intrinsic volumes, Vint, of
the dissolved non-electrolytes. Effective pressures, Pe,
in aqueous electrolyte solutions were calculated from previously determined
internal pressure data. Substitution of Pe
into the Tait-Gibson equation yielded values of Ve, the volume contraction of water due to
electrostriction, which agree well with values obtained by other methods.
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