Abstract
The simple valence-bond and molecular orbital formulae for three-centre
bonding involving four electrons and three atoms Y, A, and B are
Y 4-B - Y-A 'P, and Y---A---B
Increased-valence formulae that have been developed recently are
Y-A . B and Y . A-B
If Y and B are the same type of atom, and bond-orbitals are used as wave functions for
Y-A and A-B bonds, then the near-equivalence of the molecular orbital and
increased-valence wave functions is demonstrated.
Bond-orders (or numbers) for these and Linnett's5s6 non-pairing spatial orbital
formula
Y . A . B
are calculated.
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