Author:
Baker Murray V.,Palermo Maria C.,Skelton Brian W.,White Allan H.
Abstract
Reactions of the imido complex
Ti(NBut)Cl2(py)3
(py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclo- hexanes
(R3tach) produce the corresponding imido complexes
TiCl2(NBut)(R3tach)
(R = Et, But). The new complexes have been
characterized by n.m.r. spectroscopy and, for the R = Bu
t case, by X-ray diffraction studies. The absence of a
C3v axis of
symmetry for the new complexes allowed complete and unequivocal assignment of
their 1H n.m.r. spectra by consideration of
proton{proton coupling and nuclear Overhauser effects.
Cited by
12 articles.
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