The thermal decomposition of t-butyl isopropyl ether

Author:

Daly NJ,Ziolkowski FJ

Abstract

t-Butyl isopropyl ether decomposes in the range 409-475� by two reactions, one giving isobutene and isopropanol, the other giving propene and t-butanol. The rate constants are described by the equations kl(isobutene) = 1013.37 exp(-55530 � 450/RT) sec-1 kl(propene) = 1012.96exp(--56480 � 950/RT) sec-1 Both reactions appear unimoleoular.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Elimination kinetics and mechanisms for several 2-alkoxyacetic acids in the gas phase;Journal of Physical Organic Chemistry;1996-12

2. AM1 method study of the thermolyses of aryl t-butylamines;Journal of Molecular Structure: THEOCHEM;1995-06

3. AM1 study of the thermolysis of n-butyl-O-R;Journal of Molecular Structure: THEOCHEM;1994-03

4. Gas phase thermolysis of arylt-butyl amines;International Journal of Chemical Kinetics;1992-07

5. Substituent effects in the gas-phase thermolysis of aryl tert-butyl ethers and sulfides;International Journal of Chemical Kinetics;1990-11

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