Abstract
The rate of acetaldehyde photolysis in
presence of acetone showed an increase due to chain initiation by methyl
radicals from the photo-decomposition of the acetone. In the presence of
formaldehyde the acetaldehyde rate decreased, implying that the decomposition
of formyl radicals was slower than that of acetyl. Glyoxal photolysis at long
wavelengths confirmed previously found low ratios of H2 to CO. Added
acetaldehyde and formaldehyde decreased the rate of the photolysis possibly
owing to collisional deactivation of excited glyoxal molecules.
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8 articles.
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