Author:
Colton R,Farthing RH,McCormick MJ
Abstract
The carbonyl halides Pd(CO)Cl and Pd(CO)Br have been prepared by the action of carbon
monoxide on palladium(II) halides in aqueous hydrohalic acid solution. In
addition, the caesium salts CsPd(CO)Cl2 and CsPd(CO)Br2, and the rubidium salt RbPd(CO)Cl2, were also isolated. The corresponding iodo
complexes could not be prepared. ��� By direct interaction of the carbonyl
halides with bis(diphenylarsino)methane (dam) the compounds [Pd(dam)X]2
(X = Cl, Br) were prepared. The formulation of all
these complexes as compounds of palladium(I) was confirmed on the basis of
various physical measurements.
Cited by
47 articles.
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