Abstract
A previously described
empirical model for solvent effects is applied to kinetic, thermodynamic and
spectroscopic data selected to reflect variation in solute-solvent interactions
of a dipole-dipole character. The three parameter fit was found to describe the
solvent effect successfully in 75% of the cases considered. The choice of
basicity parameters for protic solvents is discussed, and the basicity scales
of Gutmann, Kagiya, Koppel and Palm, and Arnett, are compared. It is concluded
that an extension of the present model should take into consideration entropic effects
associated with solute-solvent interactions.
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