Abstract
The magnetic properties of tungsten
pentachloride, WCl5, and tungsten pentabromide, WBr5,
have been re-examined as a function of temperature. The anomalous magnetic
moment of each compound is rationalized on the basis of trinuclear clusters of
tungsten atoms in the compounds. Evidence is presented for the presence of one
ionic halide atom per molecular weight, the compounds thus being formulated as
[W3X12]3+X3-.
Cited by
21 articles.
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1. Ferromagnetic Spin-1/2 Dimers with Strong Anisotropy in MoCl5;Chemistry of Materials;2019-03-25
2. Tungsten Compounds;Kirk-Othmer Encyclopedia of Chemical Technology;2010-04-16
3. Of Metal Bromides from the Elements;Inorganic Reactions and Methods;2007-05-29
4. Metal-Metal Bonds in Transition Metal Compounds;Progress in Inorganic Chemistry;2007-03-09
5. Tungsten(V) Chloride (Tungsten Pentachloride);Inorganic Syntheses;2007-01-05