Author:
Sato Tadatake,Niino Hiroyuki
Abstract
Benzdiynes, which are more unsaturated than benzyne, were proposed as reactive intermediates in the pyrolyses of aromatic dianhydrides in 1966. The generation and direct observation of these highly unsaturated species has been an experimental challenge. More than 30 years later, the first direct observation of a benzdiyne, 1,4-bis(trifluoromethyl)-2,3,5,6-tetradehydrobenzene, was reported. We outline the progress in the generation and observation of benzdiynes as well as theoretical studies on the background of benzyne chemistry. Spectroscopic observation of the benzdiynes, in particular detection of an IR band due to the asymmetric stretching of the two triple bonds, in conjunction with quantum chemical computations reveals their multireference character. In connection with the studies for generating benzdiynes, the studies for generating bisarynes with extended π-systems and the most highly unsaturated cyclic C6 are briefly reviewed.
Cited by
21 articles.
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