Abstract
The stereochemistry of the
diastereoisomeric 2-methyl-1-phenylbut-3-en- 1-ols,
3,4-epoxy-2-methyl-1-phenylbutan-1-ols and 3,4-epoxy-2-methyl-1- phenylbutan-1-ones
have been established. In the photolysis of the 3,4- epoxy-2-methyl-1-phenylbutan-1-ones
the steric interaction between the C2-methyl and the C1-substituents determines
the stereochemistry of cyclization of the initially produced orthogonal
1,4-biradical intermediates.
Cited by
17 articles.
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