Abstract
The nitration of naphthalene,
1-methylnaphthalene, and 2-methylnaphthalene has been studied under a variety
of conditions. Relative rates by competition and isomer distributions have been
determined using gas chromatographic analyses. The derived partial rate factors
are discussed in terms of various nitration mechanisms and the effect of the
methyl group on reactivity in the naphthalene system.
A simple route to
1-methyl-8-nitronaphthalene is described.
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