Abstract
The relative basic
strengths of a series of substituted acetanilides in acetic acid have been
determined both potentiometrically and spectrophotometrically. The relative potentials at half-neutralization
of the bases with perchloric acid, in both acetic acid
and acetic anhydride, have been determined. Ionization constants of the bases
with perchloric acid were obtained using N,N-diethyl-2,4-dinitroaniline as indicator base. The effect
of substitution on basic strength is discussed.
Cited by
3 articles.
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