Author:
Perram JW,Hunter RJ,Wright HJL
Abstract
We extend previous
treatments of the gel model of the oxide-solution interface and solve exactly
the most general soluble case, of such an oxide in the presence of a 1 : 2-2 :
1 electrolyte, for the distribution of charge and potential across the
interface. We calculate values of the surface charge and zeta potential of the
oxides TiO2, Fe2O3, SiO2 and M203
using reasonable values of adsorption potentials and dissociation constants
taken from tables. We find, for the samples of such oxides for which high measured
charges have been reported, that we can account quantitatively for all the data
by characterizing the interface by a gel layer of thickness 20-40�. We infer
that such comprehensive agreement, and the consistency in all cases of the high
charge and low zeta potential with the theory, gives strong support to the view
that a thin surface layer distorted by the penetration of water and all types
of ions is a general feature of the oxide-solution interface.
Cited by
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