Abstract
The reactions of triphenylaluminium and
its etherate with benzophenone, acetophenone, ethyl benzoate, and benzaldehyde
have been studied. The stoicheiometry of reaction and the effect of
coordinating base were investigated. Diphenylaluminium chloride and
phenylaluminium dichloride as compared with triphenylaluminium show an enhanced
tendency to form stable complexes with carbonyl compounds. Results obtained
with benzaldehyde are relevant to the mechanism of the Meerwein-Pondorf-Verley
and Oppenauer reactions.
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16 articles.
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