Abstract
Several complexes of the
chelating ligand 6-methyl-2-thioamidopyridine have
been prepared end studied. Infrared spectra indicate that the sulphur atom of
the thioamido group is bonding in the complexes: [CoL2(H2O)2][ClO4]2, [NiL2Br2],
[CuL2]I, [Ru2L4Cl2O]Cl2, [OsL2Cl2],
[AuL][AuCl1],
and [HgLI2] whereas nitrogen bonding
occurs with [FeLCl3]2, [ZnL3][ClO4]2,
[SnLI4], and the deprotonated species [In(L-H)3].
Copper(II) was reduced to copper(I),
e.g. [CuL2][CuBr2].
Studies in the visible spectrum, magnetic measurements, and conductances in
both nitrobenzene and dimethylformamide were also made.
Cited by
21 articles.
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