Abstract
The average magnetic moment
of tris(acetylacetonato)molybdenum(III) has been
measured down to 1.5 K. In the magnetically dilute solution state the 4A2
ground state is well described by a S 3/2 spin Hamiltonian with g 1.94, g, 1.97
and D + 7.0 cm-1 or -6.3 cm-1; the ambiguity in sign can
be resolved by earlier electron spin resonance data which suggested that D is
negative. In the solid state there appears to be a very small antiferromagnetic
interaction.
Cited by
12 articles.
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