Author:
Raston CL,White AH,Yandell JK
Abstract
The crystal structure of
the title compound, NH4 [Co(NH3)4(SO3)2],3H2O,
has been redetermined using diffractometer data at 295 K and refined by
full-matrix least squares to a residual of 0.056 for 2068 'observed'
reflections. Crystals are orthorhombic, P212121,
a 10.978(4), b 17.552(7), c 6.828(3)Ǻ, Z 4. The redetermined structure
provides accurate structural data for the cobalt environment; as well, it
locates all hydrogen atoms and defines cations and water molecules un-
ambiguously. Co-S are 2.224(2), 2.221(2) Ǻ. Co-N (trans to S) (1.993(6),
2.023(6) Ǻ) are longer than the mutually trans Co-N (1.970(7), 1.977(6)
Ǻ); the difference in the former is a consequence of lattice hydrogen
bonding.
Cited by
14 articles.
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