Author:
van den Bergen A,Murray KS,West BO
Abstract
A range of molybdenum(1V)
complexes of the type Mo(che1ate)2X2 have been prepared where (chelate) =
N-substituted salicylaldimine, acetylacetone, and
8-hydroxyquinoline; X = halogen. They can be prepared by direct substitution of
chlorine from MoCl4(MeCN)2 by a
chelating group or by oxidative substitution of MoX3py3.
The magnetic and spectroscopic properties of these six-coordinate d2 complexes
are discussed.
Cited by
21 articles.
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