Fagus orientalis Yüzeyinin ZnO/TiO2/FAS-17 Bazlı Nanopartiküllerle İşlenmesi
Author:
RAMAZANOĞLU Doğu1, ÖZDEMİR Ferhat2
Affiliation:
1. DUZCE UNIVERSITY, FACULTY OF TECHNOLOGY, DEPARTMENT OF CIVIL ENGINEERING, CIVIL ENGINEERING PR. 2. KAHRAMANMARAS SUTCU IMAM UNIVERSITY, FACULTY OF FOREST
Abstract
Aim of study: In this research, the surface of Fagus orientalis (beechwood) was chosen as a substrate due to its widely used strong biostructure in the wood industry. It was functionalized with ZnO, TiO2, and FAS-17 nanoparticles to enhance its service life.
Material and methods: FAS-17 (Trimethoxysilane) and ammonium hexafluorotitanate were purchased from Sigma-Aldrich, and zinc borate from Etimine S.A. Methanol, ethyl alcohol, hydrochloric acid, sodium hydroxide, and zinc oxide were provided by TEKKIM. Characterization methods included FTIR, TG/DTA, XRD, SEM, and EDX. Hydrophobicity was determined by water contact angle using KSV Cam101. UV-Vis analysis used a Shimadzu UV-160 spectrophotometer, surface roughness was measured with a Marsurf M 300 device (ISO 4287), and color analysis was performed with a Datacolor Elrepho 450 X spectrometer (ASTM 2021).
Main results: The thermal stability of wood was significantly improved through the hydrothermal deposition of ZnO/TiO2 nanoparticles. Additionally, hydrophobization was achieved using Triethoxy-1H,1H,1H,2H,2H,2H-perfluorodecylsilane (C14H19F13O3Si), referred to as FAS-17.
Research highlights: The study demonstrated that the introduction of ZnO/TiO2 nanoparticles improved the thermal stability of wood. Furthermore, the use of FAS-17 resulted in effective hydrophobization. The thermal stability of wood was improved with ZnO/TiO2 nanoparticles. In addition, hydrophobization was supplied by FAS-17.
Publisher
Kastamonu University
Subject
General Medicine,General Chemistry
Reference41 articles.
1. Aad, R., Simic, V., Cunff, L. L., Rocha, L., Sallet,V., Sartel, C., Lusson, A., Couteaua, C. & Lerondel, G. (2013). ZnO nanowires as effective luminescent sensing materials for nitroaromatic derivatives. Nanoscale, 5, 9176-9180. 2. Ali, M. R., Abdullah, U. H., Ashaari, Z., Hamid, N. H., & Hua, L. S. (2021). Hydrothermal Modification of Wood: A Review. Polymers, 13(16), 2612. 3. ASTM, Standard Practice for Calculation of Color Tolerances and Color Differences from Instrumentally Measured Color Coordinates. (2021). 4. Báder, M., Németh, R., Sandak, J., & Sandak, A. (2020). FTIR analysis of chemical changes in wood induced by steaming and longitudinal compression. Cellulose, 27(12), 6811-6829. 5. Bennert, T., Hanson, D., Maher, A. & Vitillo, N. (2005). Influence of pavement surface type on tire/pavement generated noise. Journal of Testing and Evaluation, 33 (2), 94-100.
|
|