Superconducting Hydrides Under Pressure

Author:

Pickard Chris J.12,Errea Ion345,Eremets Mikhail I.6

Affiliation:

1. Department of Materials Science & Metallurgy, University of Cambridge, Cambridge CB3 0FS, United Kingdom;

2. Advanced Institute for Materials Research, Tohoku University, Aoba, Sendai, 980-8577, Japan

3. Fisika Aplikatua 1 Saila, Gipuzkoako Ingeniaritza Eskola, University of the Basque Country (UPV/EHU), 20018 Donostia/San Sebastián, Spain

4. Centro de Física de Materiales (CSIC-UPV/EHU), 20018 Donostia/San Sebastián, Spain

5. Donostia International Physics Center (DIPC), 20018 Donostia/San Sebastián, Spain

6. Max-Planck Institut für Chemie, Chemistry and Physics at High Pressures Group, 55020 Mainz, Germany

Abstract

The measurement of superconductivity at above 200 K in compressed samples of hydrogen sulfide and in lanthanum hydride at 250 K is reinvigorating the search for conventional high temperature superconductors. At the same time, it exposes a fascinating interplay between theory, computation, and experiment. Conventional superconductivity is well understood, and theoretical tools are available for accurate predictions of the superconducting critical temperature. These predictions depend on knowing the microscopic structure of the material under consideration, which can now be provided by computational first-principles structure predictions. The experiments at the megabar pressures required are extremely challenging, but, for some groups at least, permit the experimental exploration of materials space. We discuss the prospects for the search for new superconductors, ideally at lower pressures.

Publisher

Annual Reviews

Subject

Condensed Matter Physics,General Materials Science

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