Cold State-Selected Molecular Collisions and Reactions

Abstract

Over the past decade, and particularly the past five years, a quiet revolution has been building at the border between atomic physics and experimental quantum chemistry. The rapid development of techniques for producing cold and even ultracold molecules without a perturbing rare-gas cluster shell is now enabling the study of chemical reactions and scattering at the quantum scattering limit with only a few partial waves contributing to the incident channel. Moreover, the ability to perform these experiments with nonthermal distributions comprising one or a few specific states enables the observation and even full control of state-to-state collision rates in this computation-friendly regime: This is perhaps the most elementary study possible of scattering and reaction dynamics.