THE DYNAMICS OF “STRETCHED MOLECULES”: Experimental Studies of Highly Vibrationally Excited Molecules With Stimulated Emission Pumping

Author:

Silva Michelle1234,Jongma Rienk1234,Field Robert W1234,Wodtke Alec M1234

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, Massachusetts 02139;

2. Department of Molecular and Laser Physics, University of Nijmegen, Toernooiveld 1, NL-6525 ED Nijmegen

3. FOM-Institute for Plasma Physics Rijnhuizen Toernooiveld 1, P. O. Box 1207, NL-3430 BE Nieuwegein, The Netherlands;

4. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106;

Abstract

▪ Abstract  We review stimulated emission pumping as used to study molecular dynamics. The review presents unimolecular as well as scattering studies. Topics include intramolecular vibrational redistribution, unimolecular isomerization and dissociation, van der Waals clusters, rotational energy transfer, vibrational energy transfer, gas-surface interactions, atmospheric effects resulting from nonequilibrium vibrational excitation, and vibrational promotion of electron transfer.

Publisher

Annual Reviews

Subject

Physical and Theoretical Chemistry

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