Analysis of Lignite Using Laser-Induced Breakdown Spectroscopy

Author:

Wallis Fiona J.1,Chadwick Bruce L.1,Morrison Richard J. S.1

Affiliation:

1. Cooperative Research Centre for Clean Power From Lignite, 8/677 Springvale Rd, Mulgrave, Victoria 3170, Australia (F.J.W., B.L.C.); and Department of Chemistry, Monash University, Clayton, Victoria 3168, Australia (F.J.W., R.J.S.M.)

Abstract

The application of laser-induced breakdown spectroscopy (LIBS) to the chemical analysis of low-ash lignite has been investigated. A Nd: YAG laser (λ = 1064 nm) is used to induce emission from the ash-forming components, which is then spectrally resolved and analyzed. LIBS analyses of five inorganic components of lignite were shown to be reproducible between sample pellets at a 95% confidence level. Detection limits (in ppm) on an as-received basis of 60 (Ca and Al), 70 (Na), 90 (Fe), and 200 (Mg and Si) were obtained from a study of 30 lignite samples, each of which was interrogated by 300 laser pulses.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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