Characterization of Supported Cylinder—Planar Germanium Waveguide Sensors with Synchrotron Infrared Radiation

Author:

Vongsvivut Jitraporn1,Fernandez Jason1,Ekgasit Sanong1,Braiman Mark S.1

Affiliation:

1. Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330 Thailand (J.V., S.E.); and Chemistry Department, Syracuse University, Syracuse, New York 13244-4100 (J.F., M.S.B.)

Abstract

Cylinder–planar Ge waveguides are being developed as evanescent-wave sensors for chemical microanalysis. The only non-planar surface is a cylinder section having a 300-mm radius of curvature. This confers a symmetric taper, allowing for direct coupling into and out of the waveguide's 1-mm2 end faces while obtaining multiple reflections at the central <30-μm-thick sensing region. Ray-optic calculations indicate that the propagation angle at the central minimum has a strong nonlinear dependence on both angle and vertical position of the input ray. This results in rather inefficient coupling of input light into the off-axis modes that are most useful for evanescent-wave absorption spectroscopy. Mode-specific performance of the cylinder–planar waveguides has also been investigated experimentally. As compared to a blackbody source, the much greater brightness of synchrotron-generated infrared (IR) radiation allows a similar total energy throughput, but restricted to a smaller fraction of the allowed waveguide modes. However, such angle-selective excitation results in a strong oscillatory interference pattern in the transmission spectra. These spectral oscillations are the principal technical limitation on using synchrotron radiation to measure evanescent-wave absorption spectra with the thin waveguides.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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