Light Emission Diode Water Thermometer: A Low-Cost and Noninvasive Strategy for Monitoring Temperature in Aqueous Solutions

Author:

Thompson Sebastián A.1,Andrade Francisco J.1,Iñón Fernando A.1

Affiliation:

1. Laboratorio de Análisis de Trazas, INQUIMAE-Departamento de Química Inorgánica, Analítica y Química Física-Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires. 3er Piso, Pabellón 2, Ciudad Universitaria. (C1428EHA) Buenos Aires, Argentina

Abstract

A spectroscopic device for monitoring the temperature of aqueous solutions is presented. It uses a 950 nm light emission diode as light source and two photodiodes as detectors. Temperature is monitored following the thermally induced absorbance changes of the water–OH second overtone (∼960 nm). A linear response between the light absorbed by an aqueous solution and its temperature is found in the range from 15 to 95 °C. A prediction error of 0.1 °C and a precision of 0.07 °C in temperature measurement can be achieved. Up to 0.1 M of electrolyte concentration can be present in the solution without significantly affecting the temperature measurement. Different strategies, such as remote (noninvasive) or in situ (using a fiber-optic probe) temperature measurement, are shown, and their relative advantages are discussed.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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