Method to Determine Chemical Composition Distribution on Matte Coating Surfaces Using Raman Microscopy-Reference-Cited by-同舟云学术

Method to Determine Chemical Composition Distribution on Matte Coating Surfaces Using Raman Microscopy

Published:2000-06 Issue:6 Volume:54 Page:783-794
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Han Hank Z. Y.¹,Lee S. S.¹,Månson J.-A. E.¹,Hilborn Jons G.¹

Affiliation:

1. Polymer Laboratory (H.Z.Y.H., J.G.H.) and Laboratory of Polymers and Composites Technology (S.S.L., J.-A.E.M.), Department of Materials Science and Engineering, The Swiss Federal Institute of Technology Lausanne, Ecublens 1015, Lausanne, Switzerland

Abstract

A method to obtain quantitative information about the chemical composition spatial distribution on rough ( Ra between half a micrometer and tens of micrometers) surfaces is developed by using a Raman microscopy technique. It is tested on a wrinkled polyester-urethane-acrylate powder coating surfaces with pronounced star-patterned (mountains and valleys) structures. Raman spectra at different features on the surface are analyzed quantitatively by using a least-squares fitting method based on coating components' spectra, taking into account chemical reactions which occurred during cure. This method is able to extract the same information as qualitative analysis could from component Raman peaks when large composition heterogeneity occurs. In addition, it provides more subtle information when chemical composition distribution is less marked. This feature is particularly useful for establishing the cause of sophisticated surface structures. The origin of the surface structures is attributed to spinodal decomposition frozen by chemical reactions during cure.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702001950391

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