Prism-Based Infrared Spectrographs Using Modern-Day Detectors

Author:

Keltner Zachary1,Kayima Katherine1,Lanzarotta Adam1,Lavalle Luis1,Canepa Marina1,Dowrey Anthony E.1,Story Gloria M.1,Marcott Curtis1,Sommer André J.1

Affiliation:

1. Molecular Microspectroscopy Laboratory, Department of Chemistry and Biochemistry, Miami University, Oxford, Ohio 45056 (Z.K., K.K., A.L., L.L., M.C., A.J.S.); and The Procter and Gamble Company, Miami Valley Innovation Center, Cincinnati, Ohio 45253 (A.E.D., G.M.S., C.M.)

Abstract

A comparison of prism-based spectrographs to grating-based spectrographs is made when each of the systems is coupled to a modern-day liquid-nitrogen-cooled photovoltaic array detector. A comparison of the systems is also made using a room-temperature microbolometer array detector. Finally, infrared microspectroscopy of samples whose size is ∼10 micrometers will be demonstrated using a prism spectrograph outfitted with both types of detectors. The results of the study show that prism-based spectrographs offer an economical alternative to grating-based systems when spectral coverage is more critical than spectral resolution. The results also demonstrate that spectra with good signal-to-noise ratios can be collected on any of the systems with a total integration time of 10 seconds or less.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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