A Theoretical Discussion of the Comparative Performances of Dispersion and Fourier-Transform Interferometric Spectrometers for the Infrared Region

Author:

Sheppard N.1,Greenler R. G.1,Griffiths P. R.1

Affiliation:

1. School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, England, Department of Physics, University of Wisconsin-Milwaukee, Milwaukee, Wisconsin 53201, and Department of Chemistry, Ohio University, Athens, Ohio 45701

Abstract

A summary is given of the theoretical factors that determine the performances of dispersion and Fourier-transform (interferometric) infrared spectrometers in terms of the signal/noise ratio obtainable in relation to the time spent in signal measurement for a given spectral resolution. It is assumed that, as is normal in the infrared region of the spectrum, the performances of the spectrometers are limited by detector noise. “Trading rules” are given relating the spectral resolution to the time of spectral measurement or the signal/noise ratio for each type of instrument. It is shown that, for a given pair of dispersion and interferometric spectrometers, the latter operating with matched-throughput, the relative performance of the interferometer improves by a factor of √2 in signal/noise ratio (or 2 in time) when the resolution interval, Δ, is halved.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Cited by 11 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Norman Sheppard. 16 May 1921—10 April 2015;Biographical Memoirs of Fellows of the Royal Society;2018-08-08

2. Infrared External Reflection Spectroscopy;Surface Infrared and Raman Spectroscopy;1995

3. Surface infrared spectroscopy;Surface Science Reports;1988-05

4. Professor Norman Sheppard FRS;Spectrochimica Acta Part A: Molecular Spectroscopy;1987-01

5. Infrared spectroscopy of molecules on metal single-crystal surfaces;Journal of Electron Spectroscopy and Related Phenomena;1986-01

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