Effects of pH on the C-13 Magnetic Resonance Spectrum of Phenol-Reference-Cited by-同舟云学术

Effects of pH on the C-13 Magnetic Resonance Spectrum of Phenol

Published:1972-03 Issue:2 Volume:26 Page:220-223
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Nakashima Thomas T.¹,Maciel Gary E.¹

Affiliation:

1. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80521

Abstract

The C-13 chemical shift dependences of phenol on pH have been investigated and the shifts interpreted in terms of the phenol-phenoxide equilibrium and hydrogen bonding. In the low and high ranges of pH the carbon shifts have been related to subtle changes in the characteristics of solvent properties. The spectra were obtained using the Fourier transform technique.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/000370272774352254

Reference4 articles.

1. Solvent Effects on the C13 Chemical Shift of the Substituted Carbon Atom of Phenol

2. C13 Nuclear Magnetic Resonance Spectroscopy. II. Phenols, Anisole and Dimethoxybenzenes

3. Substituent Effects on the C13and H1Chemical Shifts in Monosubstituted Benzenes

4. Approximate Self‐Consistent Molecular‐Orbital Theory. V. Intermediate Neglect of Differential Overlap

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