Affiliation:
1. Morristown Research Laboratory, Industrial Chemicals Division, Allied Chemical Corporation, Morristown, New Jersey 17960
Abstract
The infrared spectra of trifluoroamine oxide and its 15N analogue have been measured from 4000 to 260 cm−1. Fundamental frequency assignments (based upon C3ν symmetry) made from the 14N spectrum are: ν1( a1) = 1689, ν2( a1) = 740, ν3( a1) = 528, ν4( e) = 880, and ν6( e) = 398 cm−1. Normal coordinate calculations support the assignment of the remaining fundamental ν5( e) to a band system appearing as a shoulder, about 558 cm−1, on the intense ν3( a1) fundamental.
Subject
Spectroscopy,Instrumentation
Cited by
17 articles.
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