Experimental Study of NaCl Aqueous Solutions by Raman Spectroscopy: Towards a New Optical Sensor

Author:

Đuričković Ivana1,Marchetti Mario1,Claverie Rémy1,Bourson Patrice1,Chassot Jean-Marie1,Fontana Marc D.1

Affiliation:

1. Laboratoire Matériaux Optiques, Photonique et Systèmes, University Paul Verlaine of Metz and Supélec-2 rue Edouard Belin, 57070 Metz, France (I.Đ., P.B., J.-M.C., M.D.F.); and Laboratoire Régional des Ponts et Chaussées de Nancy, Centre d'Études Techniques de l'Équipement de l'Est-71 rue de la grande haie, 54510 Tomblaine, France (I.Đ., MM., R.C.)

Abstract

Raman spectroscopy was used to study the NaCl aqueous solutions around the solid-liquid phase transition. Special attention was devoted to the modification induced by the salt on the OH stretching band of water. Investigations were carried out in the temperature range between-21 and 10 °C, for concentrations from 0 to 200 g/L. We demonstrated that micro-Raman spectroscopy can be used as a marker, allowing the determination of the salt concentration of an aqueous solution with an error close to ±5%.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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