Spectroscopic Characterization of Urea Aqueous Solutions: Experimental Phase Diagram of the Urea–Water Binary System

Author:

Durickovic Ivana1,Thiébaud Laura2,Bourson Patrice2,Kauffmann Thomas2,Marchetti Mario1

Affiliation:

1. Laboratoire Régional des Ponts et Chaussées de Nancy, Centre d'Études Techniques de l’Équipement de l'Est, 71 rue de la Grande Haie, 54510 Tomblaine, France

2. Laboratoire Matériaux Optiques, Photonique et Systèmes, University Paul Verlaine of Metz and Supélec, 2 rue Edouard Belin, 57070 Metz, France

Abstract

Raman spectroscopy was used to analyze mixtures of urea and water in order to identify the influence of the urea concentration on the solution's freezing point. Our approach consisted in the analysis of urea aqueous solutions and the determination of their phase transitions at low temperatures. Hence, Raman spectra of these solutions were acquired in a −30 to 10 °C temperature range. This enabled us to build the experimental phase diagram of the urea–water binary system.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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