Dual-Beam Thermal Lens Measurement of Condensed-Phase Sample at CO2 Laser Wavelengths: Detection of Octadecanoic Acid in Carbon Tetrachloride

Author:

Franko Mladen1,Bicanic Dane1,Bozóki Zoltán1,Jalink Henk1

Affiliation:

1. “Jožef Stefan” Institute, Jamova 39, 61111 Ljubljana, Slovenia (M.F.); Laser Photoacoustic Laboratory, Department of Agricultural Engineering and Physics, Agricultural University, Agrotechnion, Bomenweg 4, 6703 HD Wageningen, The Netherlands (D.B.); Department of Photophysics, Institute of Isotopes, Hungarian Academy of Sciences, Budapest, Hungary (Z.B.); and Centre for Plant Breeding and Reproduction Research, CPRO-DLO, P.O. Box 16, 6700 AA Wageningen, The Netherlands (H.J.)

Abstract

Detection of monobasic, straight-chain saturated fatty acid (octadecanoic C18:0) in CCl4, based on the thermal lens effect after excitation by CO2 laser radiation at 934.9 cm−1, is described for the first time. The achieved limit of detection (LOD = 0.3%) is comparable to that of the transmission infrared technique. Possibilities for further improvements in sensitivity and detection limit are also discussed.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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