Determination of Iron, Cobalt, Nickel, and Copper in Hafnium Fluoride by GF-AAS

Author:

Jaganathan James1,Aggarwal Ishwar1

Affiliation:

1. Optical Sciences Division, Code 6505, Naval Research Laboratory, Washington, D.C. 20375-5000 (J.J., I.A.); and GEO-Centers, Inc., Fort Washington, Maryland 20744 (J.J.)

Abstract

This paper describes an analytical method for the quantitation of iron, cobalt, nickel, and copper at trace levels with graphite furnace-atomic absorption spectrometry (GF-AAS) without the use of any matrix modifier or preconcentration techniques. A solution of HfF4 (10%, w/v) in HF (24%) was used for this study. The detection limits for iron, cobalt, nickel, and copper were found to be 3, 1, 3, and 2 ppb, respectively. The average precision of measurements (% RSD) for all the elements was <10%.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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