Sulfur Hexafluoride: Optimal Use as a Gas-Phase, Infrared Sensitizer

Author:

Stanley A. E.1,Ludwick L. M.1,White D.1,Andrews D. E.1,Godbey S. E.1

Affiliation:

1. Weapons Sciences Directorate, AMSMI-RD-WS-CM, Research, Development, and Engineering Center, U.S. Army Missile Command, Redstone Arsenal, Alabama 35898-5248

Abstract

Investigations into the use of sulfur hexafluoride, SF6, as a gas-phase, infrared photochemical sensitizer have revealed several interesting phenomena. The expedient use of SF6 can produce an optimal quantity of nitrated product in the gas-phase, laser-induced nitration of cyclopen-tane. The optimal utilization of sulfur hexafluoride required critical optimization of both frequency and quantity. The results are described herein.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Laser sensitized dissociation of tetramethyl germane;Journal of Photochemistry and Photobiology A: Chemistry;1996-09

2. Absorptivity of SiF4 at 1027 cm−1 for High Continuous-Wave Laser Power;Applied Spectroscopy;1996-03

3. Laser-induced selective nitration of three cycloalkanes;Journal of Photochemistry and Photobiology A: Chemistry;1995-10

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